By 鈴木, 基之, 1941- 鈴木, 基之, ; Motoyuki Suzuki
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Additional resources for Adsorption engineering
Adsorption Equilibrium In practical operations, maximum capacity of adsorbent cannot be fully utilized because of mass transfer effects involved in actual fluid-solid contacting processes. In order to estimate practical or dynamic adsorption capacity, however, it is essential, first of all, to have information on adsorption equilibrium. Then kineticanalyses are conducted based on rate processes depending on types of contacting processes. The most typical of the rate steps in solid adsorbents is the intraparticle diffusion which is treated in the next chapter.
2 17 In the table and figure, the pore s u e calculated by Doll~more'smethod 1s included Both methods approach pore size of around 13 4 I( and p/p,=O 05, and Howath and Kawazoe suggested that their method should be appl~edto measurements below p/p,=O 5 and that Dolllmore's method should be used above thls relatlve pressure Pore size dlstrlbutlons of carbon molecular sleve determlned by thls method are shown In Flg 2 18, where W- 1s the maxlmum pore volume determlned from the amount adsorbed at p/p,=O 9 Measurement o j Pore-related Properties - 10 -5 x Dollimore Horvath-Kawazoe +-x-+a7X U :.
11 (Kawai and Kawazoe, 1975). 2 one can see that a parameter, n, is not necessarily an Also from TABLE integer. n may be a function of relative magnitude of adsorbate molecular size and micropore size. From this point of view, and Suzuki and Sakoda (1982) tried to extend the D-A equation to include adsorbent which has apparent micropore size TABLE 3 2 Characteristic Values of Adsorption on MSC SA Adsorbate Wo [CC /gl n [-I E [call moll I nitrogen 2 carbon d ~ o x ~ d e 3 oxygen 4 hydrogen 5 neon 6 argon 7 krypton 8 xenon 9 methane 10 ethylene I I ethane I2 propylenc 13 n-butane 14 n-hcxanc I5 benzene 16 ethyl acetate 17 p-xylcne 18 trichlorocthylene 19 tetrahydrofuran 20 methykne chloride 2 1 cyclohexane 22 aatone 23 carbon disulfidc 24 methanol 25 ethanol 26 n-butanol 27 acctlc acid 28 ..